Delicate membranes given super strength to transform green energy tech

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Chemical engineers at The University of Queensland are harnessing an intricate building technique to produce the hyper-thin film membranes that boost the reliability, efficiency, and lifespan of key clean energy systems.

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From: The University of Queensland

Researchers have found a way to fabricate film-thin membranes imbued with super strength that could extend the durability of decarbonisation technologies.

Chemical engineers at The University of Queensland are harnessing an intricate building technique to produce the hyper-thin film membranes that boost the reliability, efficiency, and lifespan of key clean energy systems.

Dr Zhuyuan Wang and Prof Xiwang Zhang from UQ’s School of Chemical Engineering said membranes that transport ions in fuel cells, batteries, electrolysers, were often not strong enough to stand the harsh operating conditions.

“Strengthening these membranes, however, usually means trading off valuable electrochemical qualities, which affects the performance of devices they are used in,” Dr Wang said.

“Our research shows that we don’t need to make that compromise.”

Dr Wang and Professor Zhang used a ‘nanoconfinement polymerisation strategy’ to control chemical bonding reactions within tiny, nanoscale channels.

“In such a tight space, the polymers have no room to grow in a messy way,” Professor Zhang said.

“They are forced to pack neatly and tightly, which makes the membranes extra dense, very strong, and excellent at letting target ions pass through quickly and efficiently.”

The membranes achieve roughly twice the tensile strength than conventional products while maintaining excellent flexibility and can be bent 100,000 times while maintaining mechanical integrity.

Crucially, researchers said this fabrication method can be applied to other thin film technologies.

“The conductivity and selectivity of the new membranes outperform both commercial membranes and those reported in literatures, with an ion exchange capacity nearly 20 per cent higher,” Dr Wang said.

Dr Wang said the next step would be encouraging research into how nanochannel polymerisation strategy can be adapted for scalable production.

“By tweaking how we make these small pieces of film we have the potential to improve the efficiency, power output, and operational stability of a number of electrochemical devices for decarbonisation,” Dr Wang said.

The research was published in Nature Synthesis.

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Strength test for electonic membranes
Membrane strength test still
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Membrane strength test still 2
Membrane strength test still 2
Journal/
conference:
Nature Synthesis
Research:Paper
Organisation/s: The University of Queensland, The University of New South Wales, The University of Melbourne, UQ School of Chemical Engineering, ARC Centre of Excellence for Green Electrochemical Transformation of Carbon Dioxide (GetCO2), UQ Dow Centre for Sustainable Engineering Innovation
Funder: This research was conducted by the ARC Centre of Excellence for Green Electrochemical Transformation of Carbon Dioxide and funded by the Australian Government. X.Zhang thanks the Australian Research Council for his ARC Future Fellowship (FT210100593). This work was supported by resources provided by the Pawsey Supercomputing Research Centre with funding from the Australian Government and the Government of Western Australia. This research was undertaken with the assistance of resources and services from the National Computational Infrastructure (NCI), which is supported by the Australian Government. D.V.A. and K.S.N. acknowledge the support from the Ministry of Education (Singapore) under the Research Centre of Excellence programme (grant EDUN C-33-18-279-V12, the Institute for Functional Intelligent Materials (I-FIM)).
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